{"id":581,"date":"2024-11-16T09:00:00","date_gmt":"2024-11-16T01:00:00","guid":{"rendered":"https:\/\/qinghansmile.cn\/?p=581"},"modified":"2024-12-29T18:13:52","modified_gmt":"2024-12-29T10:13:52","slug":"%e6%96%87%e7%8c%ae%e9%98%85%e8%af%bb-%e7%83%ad%e6%bf%80%e5%ad%90%e6%9c%ba%e5%88%b6%e4%b8%8b%e9%ab%98%e6%95%88%e8%93%9d%e8%89%b2%e7%94%b5%e8%87%b4%e5%8f%91%e5%85%89%e7%9a%84%e5%af%b9","status":"publish","type":"post","link":"https:\/\/qinghansmile.cn\/index.php\/2024\/11\/16\/%e6%96%87%e7%8c%ae%e9%98%85%e8%af%bb-%e7%83%ad%e6%bf%80%e5%ad%90%e6%9c%ba%e5%88%b6%e4%b8%8b%e9%ab%98%e6%95%88%e8%93%9d%e8%89%b2%e7%94%b5%e8%87%b4%e5%8f%91%e5%85%89%e7%9a%84%e5%af%b9\/","title":{"rendered":"\u6587\u732e\u9605\u8bfb\u2014\u2014\u70ed\u6fc0\u5b50\u673a\u5236\u4e0b\u9ad8\u6548\u84dd\u8272\u7535\u81f4\u53d1\u5149\u7684\u5bf9\u79f0\u5206\u5b50\u8bbe\u8ba1\u7b56\u7565"},"content":{"rendered":"\t\t
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\u00a0 \u5177\u6709\u70ed\u6fc0\u5b50\u673a\u5236\u7684\u53d1\u5149\u4f53\u88ab\u8ba4\u4e3a\u662f\u6709\u673a\u53d1\u5149\u4e8c\u6781\u7ba1(oled)\u6700\u6709\u524d\u9014\u7684\u5019\u9009\u4f53\u4e4b\u4e00\u3002\u5728\u672c\u7814\u7a76\u4e2d\uff0c\u901a\u8fc7\u5c06\u4e00\u5bf9\u5494<\/b>\u5511\u57fa\u56e2\u4e0e\u4e00\u4e2a9,9 ‘ -\u53cc\u84bd\u6838<\/b>\u7ed3\u5408\uff0c\u62a5\u9053\u4e86\u4e00\u4e2a\u5177\u6709\u70ed\u6fc0\u5b50\u673a\u5236\u7684\u6df1\u84dd\u8272\u53d1\u5c04\u5668\uff0c\u53732An-PCz\u3002\u7531\u4e8e\u5bf9\u79f0\u7684\u5206\u5b50\u7ed3\u6784\u548c\u56fa\u6709\u7684\u5c40\u57df\u6fc0\u53d1\u7279\u6027\uff0c\u53ef\u4ee5\u5f62\u6210\u591a\u4e2a\u9ad8\u7a0b\u53cd\u5411\u7cfb\u7edf\u95f4\u4ea4\u53c9(hRISC)\u901a\u9053\u548c\u5927\u91cd\u53e0\u7684\u524d\u6cbf\u5206\u5b50\u8f68\u9053(FMOs)\uff0c\u4fc3\u8fdb\u4e86hRISC\u8fc7\u7a0b\u7684\u5feb\u901f\u8fdb\u884c\uff0c\u540c\u65f6\u63d0\u9ad8\u4e86\u8f90\u5c04\u8dc3\u8fc1\u901f\u7387\u3002\u7ed3\u5408\u72ec\u7279\u7684x\u586b\u5145\u6a21\u5f0f\u5e26\u6765\u7684\u5f3a\u53d1\u5149\u6027\u80fd\uff0c\u5728\u975e\u63ba\u6742\u72b6\u6001\u4e0b\u5b9e\u73b0\u4e8660.5%\u7684\u9ad8\u5149\u81f4\u53d1\u5149\u91cf\u5b50\u4ea7\u7387<\/b>\u3002\u5f15\u4eba\u6ce8\u76ee\u7684\u662f\uff0c\u672a\u63ba\u6742\u7684\u6df1\u84ddoled\u663e\u793a\u51fa10.50%\u7684\u6700\u5927\u5916\u91cf\u5b50\u6548\u7387(EQE)<\/b>\u548c\u6700\u5c0f\u7684\u6709\u6548\u6eda\u964d\uff0c\u8fd9\u662f\u8fc4\u4eca\u4e3a\u6b62\u57fa\u4e8e\u70ed\u6fc0\u5b50\u53d1\u5c04\u5668\u7684\u6df1\u84dd\u6709\u673a\u53d1\u5149\u5668\u4ef6\u7684\u6700\u9ad8\u503c\u4e4b\u4e00\u3002\u78c1\u7535\u81f4\u53d1\u5149(MEL)\u5b9e\u9a8c\u548c\u77ac\u6001\u7535\u81f4\u53d1\u5149\u6d4b\u91cf\u8bc1\u5b9e\u4e86\u9ad8EQE\u548c\u6291\u5236\u6548\u7387\u6eda\u8f6c\uff0c\u8fd9\u5f52\u56e0\u4e8e\u5feb\u901f\u7684\u201c\u70ed\u6fc0\u5b50\u201d\u901a\u9053\u3002<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t

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\u70ed\u6fc0\u5b50\u673a\u5236\uff1a<\/h4>

\u00a0 \u70ed\u6fc0\u5b50\u673a\u5236\u662f\u4e00\u79cd\u65b0\u578b\u7684\u53d1\u5149\u673a\u5236\uff0c\u5b83\u5229\u7528\u9ad8\u80fd\u4e09\u91cd\u6001\u6fc0\u5b50\uff08\u70ed\u6fc0\u5b50\uff09\u7684\u5feb\u901f\u53cd\u5411\u7cfb\u95f4\u7a9c\u8d8a\uff08hRISC\uff09\u8fc7\u7a0b\uff0c\u5c06\u80fd\u91cf\u8f6c\u79fb\u5230\u5355\u91cd\u6001\u6fc0\u5b50\uff0c\u4ece\u800c\u5b9e\u73b0\u9ad8\u6548\u7684\u7535\u81f4\u53d1\u5149\u3002<\/p>

\u4e09\u91cd\u6001\u6e6e\u706d\uff1a<\/h4>

\u00a0 \u4e09\u91cd\u6001\u6e6e\u706d\uff08Triplet-Triplet Annihilation, TTA\uff09, \u662f\u4e00\u79cd\u7279\u6b8a\u7684\u53d1\u5149\u673a\u5236\uff0c\u5b83\u6d89\u53ca\u4e24\u4e2a\u4e09\u91cd\u6001\u6fc0\u5b50\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u5f53\u4e24\u4e2a\u4e09\u91cd\u6001\u6fc0\u5b50\u9760\u8fd1\u65f6\uff0c\u5b83\u4eec\u53ef\u4ee5\u53d1\u751f\u6e6e\u706d\uff0c\u5176\u4e2d\u4e00\u4e2a\u6fc0\u5b50\u88ab\u6e6e\u706d\uff0c\u800c\u53e6\u4e00\u4e2a\u6fc0\u5b50\u88ab\u6fc0\u53d1\u5230\u5355\u91cd\u6001<\/strong>\u3002\u8fd9\u4e2a\u5355\u91cd\u6001\u6fc0\u5b50\u968f\u540e\u53ef\u4ee5\u53d1\u5c04\u5149\u5b50\uff0c\u5b9e\u73b0\u53d1\u5149\u3002<\/p>

\u5916\u90e8\u91cf\u5b50\u6548\u7387<\/h4>

\u00a0 \u5916\u90e8\u91cf\u5b50\u6548\u7387(External Quantum Efficiency, EQE)\u662f\u8861\u91cfOLED\u5668\u4ef6\u6548\u7387\u7684\u5173\u952e\u6307\u6807\uff0c\u5b83\u8868\u793a\u5668\u4ef6\u5c06\u6ce8\u5165\u7684\u7535\u5b50-\u7a7a\u7a74\u5bf9\u8f6c\u5316\u4e3a\u5149\u5b50\u7684\u6548\u7387<\/strong>\u3002<\/p>

\u5185\u90e8\u91cf\u5b50\u6548\u7387 <\/strong><\/h4>

\u00a0 \u5185\u90e8\u91cf\u5b50\u6548\u7387 (Internal Quantum Efficiency, IQE) \u662f\u8861\u91cfOLED\u5668\u4ef6\u5185\u90e8\u53d1\u5149\u6548\u7387\u7684\u6307\u6807\uff0c\u5b83\u8868\u793a\u5668\u4ef6\u5185\u90e8\u4ea7\u751f\u7684\u6fc0\u5b50\u4e2d\uff0c\u6700\u7ec8\u8f6c\u5316\u4e3a\u5149\u5b50\u7684\u6bd4\u4f8b\u3002<\/strong><\/p>

\u7b80\u5e76:<\/strong><\/h4>

\u00a0 \u7b80\u5e76 (Degeneracy) \u5728\u91cf\u5b50\u529b\u5b66\u4e2d\u6307\u7684\u662f\u5177\u6709\u76f8\u540c\u80fd\u91cf\u7684\u7535\u5b50\u6001<\/strong>\u3002<\/p>

\u524d\u7ebf\u8f68\u9053\uff1a<\/h4>

\u00a0 \u524d\u7ebf\u8f68\u9053(Frontier Molecular Orbitals\uff0cFMOs) \u662f\u6307\u6750\u6599\u7684\u6700\u9ad8\u5df2\u5360\u636e\u5206\u5b50\u8f68\u9053 (HOMO) \u548c\u6700\u4f4e\u672a\u5360\u636e\u5206\u5b50\u8f68\u9053 (LUMO)\u3002<\/strong><\/p>

\u00a0 \u5728\u4e00\u822c\u7684\u8ba1\u7b97\u7ed3\u679c\u56fe\u91cc\u9762\uff1a<\/strong><\/p>

  • \u7ea2\u8272<\/strong>\uff1a\u901a\u5e38\u8868\u793a\u8f68\u9053\u7684\u7b26\u53f7\u4e3a\u6b63\uff0c\u5373\u7535\u5b50\u4e91\u7684\u5bc6\u5ea6\u8f83\u5927\u3002<\/p><\/li>

  • \u84dd\u8272<\/strong>\uff1a\u901a\u5e38\u8868\u793a\u8f68\u9053\u7684\u7b26\u53f7\u4e3a\u8d1f\uff0c\u5373\u7535\u5b50\u4e91\u7684\u5bc6\u5ea6\u8f83\u5c0f\u3002<\/p><\/li><\/ul>

    \u632f\u5b50\u5f3a\u5ea6:<\/h4>

    \u00a0 \u632f\u5b50\u5f3a\u5ea6 (Oscillator Strength, f) \u662f\u4e00\u4e2a\u63cf\u8ff0\u5206\u5b50\u4e2d\u7535\u5b50\u8dc3\u8fc1\u6982\u7387\u7684\u7269\u7406\u91cf<\/strong>\uff0c\u5b83\u53cd\u6620\u4e86\u5206\u5b50\u5438\u6536\u6216\u53d1\u5c04\u5149\u5b50\u7684\u80fd\u529b\u3002<\/p>

    \u632f\u5b50\u5f3a\u5ea6\u7684\u610f\u4e49<\/strong>\uff1a<\/p>

    • \u8dc3\u8fc1\u6982\u7387<\/strong>\uff1a\u632f\u5b50\u5f3a\u5ea6\u8d8a\u5927\uff0c\u7535\u5b50\u8dc3\u8fc1<\/strong>\u7684\u6982\u7387\u8d8a\u9ad8\uff0c\u5373\u5206\u5b50\u5438\u6536\u6216\u53d1\u5c04\u5149\u5b50\u7684\u80fd\u529b\u8d8a\u5f3a\u3002<\/p><\/li>

    • \u5149\u8c31\u5f3a\u5ea6<\/strong>\uff1a\u632f\u5b50\u5f3a\u5ea6\u4e0e\u5149\u8c31\u5f3a\u5ea6\u6210\u6b63\u6bd4<\/strong>\uff0c\u5373\u632f\u5b50\u5f3a\u5ea6\u8d8a\u5927\uff0c\u5149\u8c31\u7684\u5f3a\u5ea6\u8d8a\u9ad8\u3002<\/p><\/li><\/ul>

      \u5f71\u54cd\u632f\u5b50\u5f3a\u5ea6\u7684\u56e0\u7d20<\/strong>\uff1a<\/p>

      • \u8dc3\u8fc1\u7c7b\u578b<\/strong>\uff1a\u4e0d\u540c\u7c7b\u578b\u7684\u8dc3\u8fc1\uff08\u4f8b\u5982\u03c0-\u03c0\u8dc3\u8fc1\u548cn-\u03c0\u8dc3\u8fc1\uff09\u5177\u6709\u4e0d\u540c\u7684\u632f\u5b50\u5f3a\u5ea6\u3002<\/p><\/li>

      • \u5206\u5b50\u7ed3\u6784<\/strong>\uff1a\u5206\u5b50\u7ed3\u6784\u4f1a\u5f71\u54cdFMOs\u7684\u80fd\u7ea7\u548c\u7a7a\u95f4\u5206\u5e03\uff0c\u4ece\u800c\u5f71\u54cd\u632f\u5b50\u5f3a\u5ea6\u3002<\/p><\/li>

      • \u6eb6\u5242\u6548\u5e94<\/strong>\uff1a\u6eb6\u5242\u6548\u5e94\u4f1a\u5f71\u54cd\u5206\u5b50\u7684FMOs\uff0c\u4ece\u800c\u5f71\u54cd\u632f\u5b50\u5f3a\u5ea6\u3002<\/p><\/li><\/ul>

        \u81ea\u7136\u8dc3\u8fc1\u8f68\u9053\uff1a<\/h4>

        \u00a0 \u81ea\u7136\u8dc3\u8fc1\u8f68\u9053\uff08Natural Transition Orbitals, NTOs\uff09\u662f\u5728\u5206\u5b50\u8f68\u9053\u7406\u8bba\u4e2d\u7528\u6765\u63cf\u8ff0\u7535\u5b50\u6fc0\u53d1\u8fc7\u7a0b\u4e2d\u7535\u5b50\u5bc6\u5ea6\u53d8\u5316\u7684\u4e00\u79cd\u91cf\u5b50\u5316\u5b66\u6982\u5ff5\u3002NTOs\u662f\u7531\u524d\u7ebf\u5206\u5b50\u8f68\u9053\uff08FMOs\uff09\u53d1\u5c55\u800c\u6765\u7684\uff0c\u5b83\u4eec\u63d0\u4f9b\u4e86\u4e00\u79cd\u66f4\u52a0\u76f4\u89c2\u7684\u65b9\u5f0f\u6765\u7406\u89e3\u7535\u5b50\u6fc0\u53d1\u548c\u5149\u5438\u6536\u8fc7\u7a0b\u3002<\/p>

        \u78f7\u5149\u654f\u5316\u5242\uff1a<\/h4>

        \u00a0 \u78f7\u5149\u654f\u5316\u5242\u662f\u4e00\u79cd\u7279\u6b8a\u7684\u5316\u5408\u7269\u6216\u6750\u6599\uff0c\u5b83\u80fd\u591f\u6709\u6548\u5730\u5c06\u80fd\u91cf\u8f6c\u79fb\u7ed9\u78f7\u5149\u4f53<\/strong>\uff0c\u4ece\u800c\u589e\u5f3a\u78f7\u5149\u4f53\u7684\u53d1\u5149\u6548\u7387\u3002\u5728\u5149\u7535\u5b50\u5b66\u548c\u5149\u5316\u5b66\u4e2d\uff0c\u78f7\u5149\u654f\u5316\u5242\u7684\u5e94\u7528\u5e7f\u6cdb\uff0c\u5c24\u5176\u662f\u5728\u6709\u673a\u53d1\u5149\u4e8c\u6781\u7ba1\uff08OLEDs\uff09\u3001\u5149\u52a8\u529b\u6cbb\u7597\u548c\u751f\u7269\u6807\u8bb0\u7b49\u9886\u57df\u3002<\/p>

        \u5fb7\u65af\u7279\u80fd\u91cf\u8f6c\u79fb\uff1a<\/h4>

        \u00a0 \u5fb7\u65af\u7279\u80fd\u91cf\u8f6c\u79fb\uff08Dexter energy transfer, DET\uff09\u673a\u7406\uff0c\u5373Dexter\u80fd\u91cf\u8f6c\u79fb\u673a\u7406\uff0c\u662f\u4e00\u79cd\u5728\u5206\u5b50\u95f4\u6216\u5206\u5b50\u5185\u7684\u80fd\u91cf\u8f6c\u79fb\u673a\u5236\u3002\u4e0eF\u00f6rster\u5171\u632f\u80fd\u91cf\u8f6c\u79fb\uff08FRET\uff09\u4e0d\u540c\uff0cDET\u662f\u4e00\u79cd\u901a\u8fc7\u7535\u5b50\u4ea4\u6362\u76f8\u4e92\u4f5c\u7528\u5b9e\u73b0\u7684\u77ed\u8ddd\u79bb\u80fd\u91cf\u8f6c\u79fb\u8fc7\u7a0b\u3002<\/p>

        \u4ee5\u4e0b\u662fDET\u673a\u7406\u7684\u51e0\u4e2a\u5173\u952e\u70b9\uff1a<\/p>

        \u57fa\u672c\u539f\u7406\uff1a<\/p>

        1. \u7535\u5b50\u4ea4\u6362<\/strong>\uff1aDET\u6d89\u53ca\u654f\u5316\u5242\u548c\u78f7\u5149\u4f53\u4e4b\u95f4\u7684\u7535\u5b50\u4ea4\u6362\u76f8\u4e92\u4f5c\u7528\u3002\u8fd9\u79cd\u76f8\u4e92\u4f5c\u7528\u901a\u5e38\u53d1\u751f\u5728\u975e\u5e38\u77ed\u7684\u8ddd\u79bb\u5185\uff08\u5c0f\u4e8e1\u7eb3\u7c73\uff09\u3002<\/p><\/li>

        2. \u4e09\u91cd\u6001-\u4e09\u91cd\u6001\u6e6e\u706d<\/strong>\uff1a\u5728DET\u8fc7\u7a0b\u4e2d\uff0c\u654f\u5316\u5242\u7684\u6fc0\u53d1\u4e09\u91cd\u6001\u4e0e\u78f7\u5149\u4f53\u7684\u57fa\u6001\u4e09\u91cd\u6001\u4e4b\u95f4\u53d1\u751f\u76f8\u4e92\u4f5c\u7528\uff0c\u5bfc\u81f4\u654f\u5316\u5242\u7684\u4e09\u91cd\u6001\u88ab\u6e6e\u706d\uff0c\u540c\u65f6\u78f7\u5149\u4f53\u88ab\u6fc0\u53d1\u5230\u4e09\u91cd\u6001\u3002<\/p><\/li><\/ol>

          \u7279\u70b9\uff1a<\/p>

          1. \u77ed\u8ddd\u79bb<\/strong>\uff1aDET\u7684\u80fd\u91cf\u8f6c\u79fb\u6548\u7387\u968f\u8ddd\u79bb\u7684\u589e\u5927\u8fc5\u901f\u4e0b\u964d\uff0c\u56e0\u6b64\u5b83\u662f\u4e00\u79cd\u77ed\u8ddd\u79bb\u80fd\u91cf\u8f6c\u79fb\u673a\u5236\u3002<\/p><\/li>

          2. \u4e0d\u9700\u8981\u5149\u8c31\u91cd\u53e0<\/strong>\uff1a\u4e0eFRET\u4e0d\u540c\uff0cDET\u4e0d\u9700\u8981\u654f\u5316\u5242\u7684\u53d1\u5c04\u5149\u8c31\u4e0e\u78f7\u5149\u4f53\u7684\u5438\u6536\u5149\u8c31\u4e4b\u95f4\u6709\u5f88\u597d\u7684\u91cd\u53e0\u3002<\/p><\/li>

          3. \u4e09\u91cd\u6001\u53c2\u4e0e<\/strong>\uff1aDET\u6d89\u53ca\u4e09\u91cd\u6001\u7684\u53c2\u4e0e\uff0c\u56e0\u6b64\u5b83\u901a\u5e38\u53d1\u751f\u5728\u542b\u6709\u4e09\u91cd\u6001\u80fd\u7ea7\u7684\u7cfb\u7edf\u4e2d\u3002<\/p><\/li><\/ol>

            \u4f5c\u7528\u673a\u5236\uff1a<\/p>

            1. \u6fc0\u53d1\u6001\u7684\u654f\u5316\u5242<\/strong>\uff1a\u654f\u5316\u5242\u9996\u5148\u901a\u8fc7\u5438\u6536\u5149\u80fd\u88ab\u6fc0\u53d1\u5230\u4e09\u91cd\u6001\u3002<\/p><\/li>

            2. \u4e09\u91cd\u6001-\u4e09\u91cd\u6001\u76f8\u4e92\u4f5c\u7528<\/strong>\uff1a\u654f\u5316\u5242\u7684\u4e09\u91cd\u6001\u4e0e\u78f7\u5149\u4f53\u7684\u57fa\u6001\u4e09\u91cd\u6001\u4e4b\u95f4\u53d1\u751f\u76f8\u4e92\u4f5c\u7528\u3002<\/p><\/li>

            3. \u80fd\u91cf\u8f6c\u79fb<\/strong>\uff1a\u901a\u8fc7\u8fd9\u79cd\u76f8\u4e92\u4f5c\u7528\uff0c\u654f\u5316\u5242\u7684\u4e09\u91cd\u6001\u80fd\u91cf\u88ab\u8f6c\u79fb\u5230\u78f7\u5149\u4f53\uff0c\u4f7f\u5176\u4ece\u57fa\u6001\u8dc3\u8fc1\u5230\u6fc0\u53d1\u4e09\u91cd\u6001\u3002<\/p><\/li>

            4. \u78f7\u5149\u4f53\u7684\u6fc0\u53d1<\/strong>\uff1a\u78f7\u5149\u4f53\u968f\u540e\u53ef\u4ee5\u901a\u8fc7\u5185\u90e8\u8f6c\u6362\u6216\u78f7\u5149\u8f90\u5c04\u56de\u5230\u5355\u91cd\u6001\uff0c\u4ea7\u751f\u53d1\u5149\u3002<\/p><\/li><\/ol>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t

              \n\t\t\t\t\t\t
              \n\t\t\t\t\t
              \n\t\t\t
              \n\t\t\t\t\t\t
              \n\t\t\t\t
              \n\t\t\t\t\t

              \u6587\u7ae0\u601d\u8def<\/h2>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t
              \n\t\t\t\t
              \n\t\t\t\t\t\t\t\t\t

              \u00a0 \u4f5c\u8005\u4e00\u5f00\u59cb\u5148\u662f\u8ba1\u7b97\u4e86\u4e00\u4e0b2An-PCz\u7684HOMO\u548cLUMO\uff0c\u786e\u5b9a\u4e86\u7535\u5b50\u6001\u5bc6\u5ea6\u3002\u7136\u540e\u53d1\u73b0HOMO\u7684\u7535\u5b50\u4e0d\u4ec5\u5bcc\u96c6\u5728\u84bd\u4e0a\uff0c\u4e5f\u5728\u65c1\u8fb9\u7684\u5494\u5511\u4e0a\uff0c\u8ba4\u4e3a\u8fd9\u52a0\u5f3a\u4e86\u7535\u8377\u8f6c\u79fb\u7684\u901f\u5ea6\uff08\u6709LE\u6001\u7684\u4ea7\u751f\uff0c\u589e\u52a0\u4e86\u901a\u9053\uff09\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u8fd8\u7b97\u4e86\u4e00\u4e0b\u81ea\u7136\u8dc3\u8fc1\u8f68\u9053\uff08NTOs\uff09\uff0c\u7531Kasha\u89c4\u5219\u548c\u8f83\u5c0f\u7684\u632f\u5b50\u5f3a\u5ea6\u5224\u65ad\u51faS2\u548cT2\u7684\u4e0d\u5408\u7406\uff0c\u8ba4\u4e3a\u4ec5\u4ec5\u53ea\u662f\u4e00\u4e2a\u7535\u8377\u8f6c\u79fb\u6001\u3002<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t

              \n\t\t\t\t
              \n\t\t\t\t\t\t\t\t\t\t\t\t
              \n\t\t\t\t\t\t\t\t\t\t
              \"\"<\/div>\t\t\t\t\t\t\t\t\t\t\t
              FMOs\u548cNTOs<\/figcaption>\n\t\t\t\t\t\t\t\t\t\t<\/figure>\n\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t
              \n\t\t\t\t
              \n\t\t\t\t\t\t\t\t\t

              \u00a0 \u968f\u540e\uff0c\u4f5c\u8005\u53c8\u901a\u8fc7TD-DFT\u8ba1\u7b97\u4e86\u4e00\u4e0b\u5404\u4e2a\u80fd\u7ea7\u4e4b\u95f4\u7684\u80fd\u91cf\uff0c\u5f97\u5230T1\u548cT3\u7684\u80fd\u91cf\u5dee\u4ee5\u53caT2\u548cT3\u7684\u80fd\u91cf\u5dee\u4e3a0.96eV\u548c0.92eV\uff0c\u7531\u6b64\u63a8\u65ad\u51fa\u8f83\u5c0f\u7684\u5185\u8f6c\u6362\uff0c\u5168\u90e8\u8fdb\u884c\u53cd\u7cfb\u95f4\u7a9c\u8d8a\uff08hRISC\uff09\uff0c\u968f\u540e\u53c8\u6839\u636e\u5355\u6676\u884d\u5c04\u5f97\u51fa2An-PCz\u6676\u4f53\u7684\u7ed3\u6784\u4e3aX\u805a\u96c6\uff0c\u5e76\u4e14\u5e73\u9762\u4e0a\u7684\u8ddd\u79bb\u8f83\u8fdc\uff0c\u56e0\u6b64\u6392\u9664Dexter\u80fd\u91cf\u8f6c\u79fb\u7b49\u56e0\u7d20\u5e72\u6270\uff0c\u6fc0\u5b50\u90fd\u8fdb\u884c\u8f90\u5c04\u8dc3\u8fc1\u3002<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t

              \n\t\t\t\t
              \n\t\t\t\t\t\t\t\t\t\t\t\t
              \n\t\t\t\t\t\t\t\t\t\t
              \"\"<\/div>\t\t\t\t\t\t\t\t\t\t\t
              \u80fd\u7ea7\u56fe\u548c\u805a\u96c6\u6a21\u5f0f<\/figcaption>\n\t\t\t\t\t\t\t\t\t\t<\/figure>\n\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t
              \n\t\t\t\t
              \n\t\t\t\t\t\t\t\t\t

              \u00a0 \u4f5c\u8005\u4e3a\u63a2\u7a76\u57fa\u4e8e 2An-PCz \u7684\u975e\u63ba\u6742 OLED \u7684\u7535\u81f4\u53d1\u5149\u6027\u80fd\u3001\u78c1\u81f4\u7535\u81f4\u53d1\u5149 (MEL) \u5b9e\u9a8c\u548c\u77ac\u6001\u7535\u81f4\u53d1\u5149\u7279\u6027\u3002<\/span>\u5236\u5907\u4e86\u591a\u5c42\u7ed3\u6784\u7684\u975e\u63ba\u6742 OLED\uff0c\u5176\u4e2d 2An-PCz \u4f5c\u4e3a\u53d1\u5149\u5c42\uff1b<\/span>\u975e\u63ba\u6742 OLED \u5b9e\u73b0\u4e86 10.5% \u7684\u6700\u5927\u5916\u91cf\u5b50\u6548\u7387 (EQE)\uff0c\u5e76\u4e14\u5728\u4eae\u5ea6\u4e3a 1000 cd m\u22122 \u65f6\u4ecd\u4fdd\u6301 10.0% \u7684 EQE\uff0c\u6548\u7387\u6eda\u964d\u4ec5\u4e3a 4.8%\uff1b<\/span>\u78c1\u573a\u5b9e\u9a8c\u8868\u660e\uff0c\u201c\u70ed\u6fc0\u5b50\u201d \u673a\u5236\u662f 2An-PCz \u53d1\u5149\u7684\u4e3b\u8981\u673a\u5236\uff0c\u800c\u975e\u4e09\u91cd\u6001\u6e6e\u706d (TTA) \u673a\u5236<\/strong>\uff1b<\/span>\u77ac\u6001\u7535\u81f4\u53d1\u5149\u6d4b\u91cf\u4e5f\u8bc1\u5b9e\u4e86 TTA \u673a\u5236\u5728\u5668\u4ef6\u4e2d\u8d77\u7684\u4f5c\u7528\u5f88\u5c0f\uff0c\u201c\u70ed\u6fc0\u5b50\u201d \u901a\u9053\u7684\u52a0\u901f\u662f\u9ad8 EQE \u548c\u4f4e\u6548\u7387\u6eda\u964d\u7684\u4e3b\u8981\u539f\u56e0\u3002<\/span><\/p>

              \u00a0 2An-PCz \u662f\u4e00\u79cd\u5177\u6709\u9ad8\u6548\u7387\u3001\u4f4e\u6548\u7387\u6eda\u964d\u548c\u9ad8\u8272\u7eaf\u5ea6\u7684\u6df1\u84dd\u8272 \u201c\u70ed\u6fc0\u5b50\u201d \u53d1\u5149\u6750\u6599\uff0c\u5728\u5236\u5907\u9ad8\u6027\u80fd\u6df1\u84dd\u8272 OLED \u65b9\u9762\u5177\u6709\u5de8\u5927\u6f5c\u529b\u3002<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t

              \n\t\t\t\t
              \n\t\t\t\t\t\t\t\t\t\t\t\t
              \n\t\t\t\t\t\t\t\t\t\t
              \"\"<\/div>\t\t\t\t\t\t\t\t\t\t\t
              EL\u76f8\u5173\u63a2\u7a76\u5b9e\u9a8c<\/figcaption>\n\t\t\t\t\t\t\t\t\t\t<\/figure>\n\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t
              \n\t\t\t\t\t\t
              \n\t\t\t\t\t
              \n\t\t\t
              \n\t\t\t\t\t\t
              \n\t\t\t\t
              \n\t\t\t\t\t

              \u5c0f\u7ed3<\/h2>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t
              \n\t\t\t\t\t\t
              \n\t\t\t\t\t
              \n\t\t\t
              \n\t\t\t\t\t\t
              \n\t\t\t\t
              \n\t\t\t\t\t\t\t\t\t

              \u00a0 \u8fd9\u7bc7\u6587\u732e\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u6df1\u84dd\u8272 “\u70ed\u6fc0\u5b50” \u53d1\u5149\u6750\u6599 2An-PCz\uff0c\u5e76\u5bf9\u5176\u5149\u7535\u7279\u6027\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\u3002\u4e3b\u8981\u53d1\u73b0\u5982\u4e0b\uff1a<\/p>

              \u5bf9\u79f0\u5206\u5b50\u8bbe\u8ba1\u7b56\u7565\uff1a<\/h4>

              \u00a0\u901a\u8fc7\u5c06\u4e00\u5bf9\u5494\u5511\u57fa\u56e2\u4e0e 9,9′-\u8054\u84bd\u6838\u76f8\u7ed3\u5408\uff0c\u5b9e\u73b0\u4e86 2An-PCz \u7684\u5bf9\u79f0\u5206\u5b50\u7ed3\u6784\uff0c\u8fd9\u8d4b\u4e88\u4e86\u5176\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u548c\u5149\u5b66\u7279\u6027\u3002
              \u9ad8\u6548\u7684 “\u70ed\u6fc0\u5b50” \u673a\u5236\uff1a 2An-PCz \u5177\u6709\u591a\u4e2a\u9ad8\u80fd\u7ea7\u53cd\u7cfb\u95f4\u7a9c\u8d8a (hRISC) \u901a\u9053\u548c\u5927\u7684\u524d\u7ebf\u5206\u5b50\u8f68\u9053 (FMO) \u91cd\u53e0\uff0c\u8fd9\u4fc3\u8fdb\u4e86\u5feb\u901f hRISC \u8fc7\u7a0b\u5e76\u589e\u5f3a\u4e86\u8f90\u5c04\u8dc3\u8fc1\u901f\u7387\u3002<\/p>

              \u4f18\u5f02\u7684\u5149\u7269\u7406\u6027\u80fd\uff1a<\/h4>

              \u00a0 2An-PCz \u5728\u975e\u63ba\u6742\u72b6\u6001\u4e0b\u5b9e\u73b0\u4e86 60.5% \u7684\u5149\u81f4\u53d1\u5149\u91cf\u5b50\u4ea7\u7387 (PLQY)\uff0c\u8fd9\u662f\u6709\u673a\u975e\u63ba\u6742\u6df1\u84dd\u8272\u8584\u819c\u4e2d\u7684\u6700\u9ad8\u503c\u4e4b\u4e00\u3002<\/p>

              \u9ad8\u6548\u7387\u7684\u6df1\u84dd\u8272 OLED\uff1a<\/h4>

              \u00a0 \u57fa\u4e8e 2An-PCz \u7684\u975e\u63ba\u6742 OLED \u5b9e\u73b0\u4e86 10.5% \u7684\u6700\u5927\u5916\u91cf\u5b50\u6548\u7387 (EQE)\uff0c\u5e76\u4e14\u6548\u7387\u6eda\u964d\u975e\u5e38\u4f4e\uff0c\u8fd9\u662f\u57fa\u4e8e “\u70ed\u6fc0\u5b50” \u6750\u6599\u7684\u6df1\u84dd\u8272 OLED \u4e2d\u7684\u6700\u9ad8\u503c\u4e4b\u4e00\u3002<\/p>

              “\u70ed\u6fc0\u5b50” \u673a\u5236\u7684\u8bc1\u636e\uff1a<\/h4>

              \u00a0 \u78c1\u573a\u5b9e\u9a8c\u548c\u77ac\u6001\u7535\u81f4\u53d1\u5149\u6d4b\u91cf\u8868\u660e\uff0c”\u70ed\u6fc0\u5b50” \u673a\u5236\u662f 2An-PCz \u53d1\u5149\u7684\u4e3b\u8981\u673a\u5236\uff0c\u800c\u975e\u4e09\u91cd\u6001\u6e6e\u706d (TTA) \u673a\u5236\u3002

              \u00a0 \u8fd9\u9879\u5de5\u4f5c\u5efa\u7acb\u4e86\u4e00\u79cd\u5f00\u53d1\u9ad8\u6548\u6df1\u84dd\u8272 “\u70ed\u6fc0\u5b50” \u53d1\u5149\u6750\u6599\u7684\u521b\u65b0\u65b9\u6cd5\uff0c\u5e76\u4e3a\u5236\u5907\u9ad8\u6027\u80fd\u6df1\u84dd\u8272 OLED \u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t

              \n\t\t\t\t\t\t
              \n\t\t\t\t\t
              \n\t\t\t
              \n\t\t\t\t\t\t
              \n\t\t\t\t
              \n\t\t\t\t\t

              \u751f\u8bcd & \u53e5\u6cd5<\/h2>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t
              \n\t\t\t\t\t\t
              \n\t\t\t\t\t
              \n\t\t\t
              \n\t\t\t\t\t\t
              \n\t\t\t\t
              \n\t\t\t\t\t\t\t\t\t

              Intriguingly\/Interestingly, \u6709\u8da3\u7684\u662f<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"

              \u6982\u8ff0 \u00a0 \u5177\u6709\u70ed\u6fc0\u5b50\u673a\u5236\u7684\u53d1\u5149\u4f53\u88ab\u8ba4\u4e3a\u662f\u6709\u673a\u53d1\u5149\u4e8c\u6781\u7ba1(oled)\u6700\u6709\u524d\u9014\u7684\u5019\u9009\u4f53\u4e4b\u4e00\u3002\u5728\u672c\u7814\u7a76\u4e2d\uff0c\u901a\u8fc7\u5c06\u4e00\u5bf9 […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[19],"tags":[],"class_list":["post-581","post","type-post","status-publish","format-standard","hentry","category-19"],"_links":{"self":[{"href":"https:\/\/qinghansmile.cn\/index.php\/wp-json\/wp\/v2\/posts\/581","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/qinghansmile.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/qinghansmile.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/qinghansmile.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/qinghansmile.cn\/index.php\/wp-json\/wp\/v2\/comments?post=581"}],"version-history":[{"count":8,"href":"https:\/\/qinghansmile.cn\/index.php\/wp-json\/wp\/v2\/posts\/581\/revisions"}],"predecessor-version":[{"id":594,"href":"https:\/\/qinghansmile.cn\/index.php\/wp-json\/wp\/v2\/posts\/581\/revisions\/594"}],"wp:attachment":[{"href":"https:\/\/qinghansmile.cn\/index.php\/wp-json\/wp\/v2\/media?parent=581"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/qinghansmile.cn\/index.php\/wp-json\/wp\/v2\/categories?post=581"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/qinghansmile.cn\/index.php\/wp-json\/wp\/v2\/tags?post=581"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}